Reports: Antwerp 3-2 Barcelona
Teenager Arthur Vermeeren put Antwerp ahead after just 90 seconds, before Barcelona equalised before half-time through Ferran Torres.
Antwerp led again via Vincent Janssen, only for Marc Guiu, 17, to seemingly grab a point in the 91st minute.
But from the kick-off Antwerp surged downfield and won the game through another teenager, George Ilenikhena.
Antwerp had lost all five of their previous Group H matches on their Champions League debut and had already been eliminated from European competition.
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